Identify the anode,cathode,positive electrode,and negative electrode for the $Daniell$ cell $(Zn-Cu)$ and the $Copper-Silver$ $(Cu-Ag)$ cell.

  • A
    $Daniell$ cell: Anode $(Zn)$,Cathode $(Cu)$,Positive $(Cu)$,Negative $(Zn)$; $Cu-Ag$ cell: Anode $(Cu)$,Cathode $(Ag)$,Positive $(Ag)$,Negative $(Cu)$
  • B
    $Daniell$ cell: Anode $(Cu)$,Cathode $(Zn)$,Positive $(Zn)$,Negative $(Cu)$; $Cu-Ag$ cell: Anode $(Ag)$,Cathode $(Cu)$,Positive $(Cu)$,Negative $(Ag)$
  • C
    $Daniell$ cell: Anode $(Zn)$,Cathode $(Cu)$,Positive $(Zn)$,Negative $(Cu)$; $Cu-Ag$ cell: Anode $(Cu)$,Cathode $(Ag)$,Positive $(Cu)$,Negative $(Ag)$
  • D
    $Daniell$ cell: Anode $(Cu)$,Cathode $(Zn)$,Positive $(Cu)$,Negative $(Zn)$; $Cu-Ag$ cell: Anode $(Ag)$,Cathode $(Cu)$,Positive $(Ag)$,Negative $(Cu)$

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The $Cu^{+}$ ion is not stable in aqueous solution. For the disproportionation reaction,what is the $E^o$ value in $V$? (Given: $E^o_{Cu^{2+} | Cu^{+}} = 0.15 \, V$; $E^o_{Cu^{2+} | Cu} = 0.34 \, V$)

For the Galvanic cell:
$Ag_{(s)} \, | \, Ag_2C_2O_{4(s)} \, | \, C_2O_4^{2-} (0.02 \ M) \, || \, Ag^{+}(0.5 \ M) \, | \, Ag_{(s)}$
$EMF$ of the cell is $0.264 \ V$ at $25 \ ^oC$. The $K_{sp}$ of $Ag_2C_2O_{4(s)}$ is:
$[Given: \frac{2.303RT}{F} = 0.06, \ \log 2 = 0.3]$

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